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624-75-9 - Iodoacetonitrile, 97% - L03634 - Alfa Aesar

L03634 Iodoacetonitrile, 97%

CAS-Nummer
624-75-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 41,00
50g 126,00
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Iodoacetonitrile, 97%

MDL
MFCD00001886
EINECS
210-860-0

Chemische Eigenschaften

Formel
C2H2IN
Molmasse
166.95
Siedepunkt
70-72°/10mm
Flammpunkt
86°(186°F)
Dichte
2.306
Brechungsindex
1.5740
Sensitivität
Light Sensitive
Löslichkeit
Soluble in benzene, alcohol, acetone, ether. Slightly soluble in water. Insoluble in hexane.

Anwendungen

Iodoacetonitrile is used for alkylation of nucleophiles. It undergoes Reformatsky and Wittig-type reactions with aldehydes.

Bemerkungen

Light Sensitive. Store at 4°C. Incompatible with reducing agents, light and bases. Store away from strong bases.

Literaturverweise

Paul G. Wenthold. Determination of the proton affinities of bromo- and iodoacetonitrile using the kinetic method with full entropy analysis.Journal of the American Society for Mass Spectrometry.2000, 11 601-605.

W. C. Kupferschmidt; R. B. Jordan. Reactions of chromium(II) with chloro- and iodoacetonitrile and their pentaamminecobalt(III) complexes.J. Am. Chem. Soc..1984, 106 (4), 991-995.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H302-H312-H332-H314-H318

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210u-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1734628
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
AM0740000

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