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107-37-9 - Allyltrichlorosilane, 95% - L03703 - Alfa Aesar

L03703 Allyltrichlorosilane, 95%

CAS-Nummer
107-37-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 36,67
25g 112,83
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Allyltrichlorosilane, 95%

MDL
MFCD00000486
EINECS
203-485-9

Chemische Eigenschaften

Formel
C3H5Cl3Si
Molmasse
175.52
Siedepunkt
117-118°
Flammpunkt
18°(64°F)
Dichte
1.211
Brechungsindex
1.4490
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in THF, toluene, benzene. Reacts with water.

Anwendungen

Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.

Bemerkungen

Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and moisture. Incompatible with water.

Literaturverweise

Sh? Kobayashi; Chikako Ogawa; Hideyuki Konishi and Masaharu Sugiura. Chiral Sulfoxides as Neutral Coordinate-Organocatalysts in Asymmetric Allylation of N-Acylhydrazones Using Allyltrichlorosilanes.J. Am. Chem. Soc.2003, 125 (22), 6610-6611.

Ryoji Hirabayashi; Chikako Ogawa; Masaharu Sugiura and Sh? Kobayashi. Highly Stereoselective Synthesis of Homoallylic Amines Based on Addition of Allyltrichlorosilanes to Benzoylhydrazones.J. Am. Chem. Soc.2001, 123 (39), 9493-9499.

Allyltrichlorosilanes react with aldehydes in DMF without a catalyst to give high yields of the corresponding homoallylic alcohols, for example allyltrichlorosilane with benzaldehyde gives 1-phenyl-3-buten-1-ol and with cinnamaldehyde gives 1-phenyl-1,5-hexadien-3-ol, both in high yield: Tetrahedron Lett., 34, 3453 (1993); J. Org. Chem., 59, 6620 (1994).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1743449
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
VV1530000

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