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123-39-7 - N-Methylformamide, 99% - N-Formylmethylamine - L03908 - Alfa Aesar

L03908 N-Methylformamide, 99%

CAS-Nummer
123-39-7
Synonyme
N-Formylmethylamine

Größe Preis ($) Menge Verfügbarkeit
50g 17,91
250g 33,89
1000g 75,40
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N-Methylformamide, 99%

MDL
MFCD00003280
EINECS
204-624-6

Chemische Eigenschaften

Formel
C2H5NO
Molmasse
59.07
Schmelzpunkt
-4°
Siedepunkt
181-185°
Flammpunkt
98°(208°F)
Dichte
1.018
Brechungsindex
1.4320
Löslichkeit
Miscible with water, acetone and ethanol. Immiscible with ether.

Anwendungen

N-Methylformamide is used to prepare methyl isocyanate. It is used as an extraction solvent for aromatic hydrocarbons and acts as a ligand in coordination chemistry. It is employed as a solvent in oil refineries and in aluminum electrolytic capacitors. Further, it is used as a reagent in organic synthesis. In addition to this, it is used as an investigational anticancer drug and an intermediate in the production of some pharmaceutical compounds.

Bemerkungen

Incompatible with strong oxidizing agents, acids, bases and acid chlorides.

Literaturverweise

Reagent for replacement of an activated chlorine in an aromatic or heteroaromatic ring by the methylamino group: Synthesis, 39 (1980).

Precursor of methyl isocyanide (highly toxic!), by dehydration with tosyl chloride in pyridine: Org. Synth. Coll., 5, 772 (1973).

Emets, V. V.; Damaskin, B. B. Two-dimensional pressure of chemisorbed dimethylformamide and N-methylformamide molecules at Ga-, (In-Ga)-, and (Tl-Ga)-electrodes. Russ. J. Electrochem. 2015, 51 (8), 789-795.

Bunkan, A. J. C.; Hetzler, J.; Mikoviny, T.; Wisthaler, A.; Nielsen, C. J.; Olzmann, M. The reactions of N-methylformamide and N,N-dimethylformamide with OH and their photo-oxidation under atmospheric conditions: experimental and theoretical studies. Phys. Chem. Chem. Phys. 2015, 17, 7046-7059.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H360-H312

May damage fertility or the unborn child. Harmful in contact with skin.

Sicherheitshinweise: P201-P280-P281-P312-P363-P308+P313-P322-P302+P352-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Specific measures (see label). IF ON SKIN: Wash with plenty of soap and water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,6076
Beilstein
1098352
Harmonized Tariff Code
2924.19
TSCA
Yes
RTECS
LQ3000000

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