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5296-64-0 - Allyl phenyl sulfide, 97% - L04771 - Alfa Aesar

L04771 Allyl phenyl sulfide, 97%

CAS-Nummer
5296-64-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 59,60
50g 231,00
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Allyl phenyl sulfide, 97%

MDL
MFCD00014957
EINECS
226-142-5

Chemische Eigenschaften

Formel
C9H10S
Molmasse
150.24
Siedepunkt
223-225°
Flammpunkt
>98°(208°F)
Dichte
1.024
Brechungsindex
1.5740

Literaturverweise

The lithiated derivative can react with electrophiles at either the ɑ- or - postion. It was found that conversion of the organolithium to an organotitanium reagent, by reaction with Ti(O-iPr)4, followed by reaction with e.g. cyclohexanecarboxaldehyde resulted in regioselective reaction at theɑ-position to give the corresponding hydroxy sulfide: Bull. Chem. Soc. Jpn., 57, 2781 (1984). For review of allylic and benzylic carbanions substituted by heteroatoms, see: Org. React., 27, 1 (1982).

/n

Grignard reagents can be allylated with allylic sulfides in the presence of a Ni or Pd catalyst: Tetrahedron Lett., 3425 (1979).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H312-H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Sicherheitshinweise: P260u-P201-P280h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/clothing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1856940
Harmonized Tariff Code
2930.90
TSCA
No

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