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776-99-8 - 3,4-Dimethoxyphenylacetone, 97% - 1-(3,4-Dimethoxyphenyl)-2-propanone - Methyl veratryl ketone - L05477 - Alfa Aesar

L05477 3,4-Dimethoxyphenylacetone, 97%

CAS-Nummer
776-99-8
Synonyme
1-(3,4-Dimethoxyphenyl)-2-propanone
Methyl veratryl ketone

Größe Preis ($) Menge Verfügbarkeit
10g 35,43
50g 92,00
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3,4-Dimethoxyphenylacetone, 97%

MDL
MFCD00008772
EINECS
212-285-0

Chemische Eigenschaften

Formel
C11H14O3
Molmasse
194.23
Siedepunkt
154-158°/12mm
Flammpunkt
>110°(230°F)
Dichte
1.115
Brechungsindex
1.5358
Löslichkeit
Insoluble in water.

Anwendungen

3,4-Dimethoxyphenylacetone was used as starting material in the synthesis of α-methyl-dopa, an important nonproteogenic α-amino acid for pharmaceutical applications. 3,4-Dimethoxyphenylacetone undergoes asymmetric amination catalyzed by Brevibacterium linens IFO 12141 strain to yield corresponding optically active amine

Bemerkungen

Stable under normal temperatures and pressures. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.

Literaturverweise

W H Boesten et. al. Asymmetric strecker synthesis of alpha-amino acids via a crystallization-induced asymmetric transformation using (R)-phenylglycine amide as chiral auxiliary. Organic letters. 2001, 3,(8), 1121-1124.

Nakamichi K, et al. Asymmetric amination of 4-methoxyphenylacetone and its related compounds with microorganisms. Appl. Microbiol. Biotechnol. 1990, 33,(6), 637-640.

Weitere Referenzen

Beilstein
1107410
Harmonized Tariff Code
2914.50
TSCA
No
RTECS
UC1795500

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