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4-Methyl-1-pentyne, is used as a polymer matrix together with synthesized NH2-MIL 53 metal organic framework (MOF) as a filler were used to fabricate a mixed matrix membrane (MMM). It is also used in addition reactions which are typical in alkyne reactions such as halogenation, hydrogenation, hydrohalogenation, hydration, oxidative cleavage, nitrile formation and acidity of terminal alkynes. Polymerisation and substitution reactions are also useful in chemical synthesis.
W Tsang. Rate and mechanism of thermal decomposition of 4-methyl-l-pentyne in a single-pulse shock tube. International Journal of Chemical Kinetics. 2004, 2,(1), 23-36.
T Masuda.; M Kawasaki.; Y Okano.; T Higashimura. Polymerization of methylpentynes by transition metal catalysts: monomer structure, reactivity, and polymer properties. Polymer Journal. 1982, 14,(1), 371-377.
Gefahrenhinweise (EU): H225-H304
Highly flammable liquid and vapour. May be fatal if swallowed and enters airways.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.