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86-38-4 - 6,9-Dichloro-2-methoxyacridine, 98% - 3,9-Dichloro-7-methoxyacridine - L05913 - Alfa Aesar

L05913 6,9-Dichloro-2-methoxyacridine, 98%

CAS-Nummer
86-38-4
Synonyme
3,9-Dichloro-7-methoxyacridine

Größe Preis ($) Menge Verfügbarkeit
5g 29,30
25g 92,40
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6,9-Dichloro-2-methoxyacridine, 98%

MDL
MFCD00005028
EINECS
201-666-7

Chemische Eigenschaften

Formel
C14H9Cl2NO
Molmasse
278.14
Schmelzpunkt
163-165°
Löslichkeit
Insoluble in water.

Anwendungen

6,9-Dichloro-2-methoxyacridine is used to prepare 6-chloro-2-methoxy-acridin-9-ylamine by reacting with phenol and ammonium carbonate. It is used in the preparation of 9-amino-6-chloro-2-methoxyacridine, N'-(6-Chloro-2-methoxy-acridin-9-yl)-heptylamine and N,N'-bis-(6-chloro-2-methoxy-acridin-9-yl)-hexane-1,6-diamine. Further, it is involved in the preparation of 4-aminoquinoline and 9-aminoacridine derivatives by reaction with quinolizidinylalkylamines.

Bemerkungen

Incompatible with oxidizing agents.

Literaturverweise

Staderini, M.; Bolognesi, M. L.; Menéndez, J. C. Lewis Acid-Catalyzed Generation of C-C and C-N Bonds on pi-Deficient Heterocyclic Substrates. Adv. Synth. Catal. 2015, 357 (1), 185-195.

Wang, T.; Goodall, M. L.; Gonzales, P.; Sepulveda, M.; Martin, K. R.; Gately, S.; MacKeigan, J. P. Synthesis of Improved Lysomotropic Autophagy Inhibitors. J. Med. Chem. 2015, 58 (7), 3025-3035.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H334-H317-H335

Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation.

Sicherheitshinweise: P284-P261-P280a-P305+P351+P338-P405-P501a

Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
226309
Harmonized Tariff Code
2933.79
TSCA
No

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