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(^+)-trans-1,2-Diaminocyclohexane is employed in the synthesis of macrocyclic [3+3] hexa Schiff base. It also plays an important role in the preparation of multidentate ligands, chiral auxiliaries and chiral stationary phases. Further, it is used to prepare [2+2] macrocyclization by reacting with aliphatic dialdehydes. In addition to this, it acts as a chiral ligand, which finds application in asymmetric catalysis.
Francesconi, O.; Gentili, M.; Bartoli, F.; Bencini, A.; Conti, L.; Giorgi, C.; Roelens, S. Phosphate binding by a novel Zn(II) complex featuring a trans-1,2-diaminocyclohexane ligand. Effective anion recognition in water. Org. Biomol. Chem. 2015, 13, 1860-1868.
Someshwar, N.; Ramanathan, C. R. Resolution of (±)-2,2'-dihydroxy-1,1'-binaphthyl-3,3'-dicarboxylic acid using (1R,2R)-trans-cyclohexane-1,2-diamine. Tetrahedron: Asymmetry 2015, 26 (20), 1209-1213.
Gefahrenhinweise (EU): H227-H314-H318
Combustible liquid. Causes severe skin burns and eye damage. Causes serious eye damage.
Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: