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5911-08-0 - (Chloromethyl)cyclopropane, 97% - Cyclopropylmethyl chloride - L06986 - Alfa Aesar

L06986 (Chloromethyl)cyclopropane, 97%

CAS-Nummer
5911-08-0
Synonyme
Cyclopropylmethyl chloride

Größe Preis ($) Menge Verfügbarkeit
5g 69,30
25g 261,00
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(Chloromethyl)cyclopropane, 97%

MDL
MFCD00001307
EINECS
227-632-1

Chemische Eigenschaften

Formel
C4H7Cl
Molmasse
90.55
Schmelzpunkt
-91°
Siedepunkt
87-89°
Flammpunkt
-1°(30°F)
Dichte
0.980
Brechungsindex
1.4360
Löslichkeit
Not miscible in water.

Anwendungen

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.

Literaturverweise

V.F.Kalasinsky; C. J.Wurrey. Vibrational spectra and conformations of (chloromethyl)cyclopropane and epichlorohydrin. Journal of Raman Spectroscopy. 1980, 9,(5), 315-323.

 

N.Heineking; J.U.Grabow; I.Merke. Molecular beam Fourier transform microwave spectra of (chloromethyl)cyclopropane and (chloromethyl)oxirane. Journal of Molecular Structure. 2002, 612,(2-3), 231-244.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H302-H315-H319-H335

Highly flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P280h-P243-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. Take precautionary measures against static discharge. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
635697
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2903.89
TSCA
No

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