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Oxidation of the Na salts of sec-nitro-compounds with ferricyanide in the presence of nucleophiles such as CN-, NO2 - or benzenesulfinate anion provides a valuable route to ɑ-nitronitriles, gem-dinitro-compounds, ɑ-nitrosulfones, etc.: J. Org. Chem., 48, 332 (1983). ɑ-Nitronitriles react with nitronate anions to give ß-nitronitriles in excellent yield: J. Org. Chem., 49, 358 (1984):/n
Gefahrenhinweise (EU): H227-H315-H319-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.