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759-24-0 - Diethyl tert-butylmalonate, 97% - tert-Butylmalonic acid diethyl ester - L09131 - Alfa Aesar

L09131 Diethyl tert-butylmalonate, 97%

CAS-Nummer
759-24-0
Synonyme
tert-Butylmalonic acid diethyl ester

Größe Preis ($) Menge Verfügbarkeit
1g 30,40
5g 96,90
25g 392,00
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Diethyl tert-butylmalonate, 97%

MDL
MFCD00009152
EINECS
212-067-5

Chemische Eigenschaften

Formel
C11H20O4
Molmasse
216.28
Siedepunkt
102-104°/11mm
Flammpunkt
90°(194°F)
Dichte
0.978
Brechungsindex
1.4250
Löslichkeit
Immiscible with water.

Anwendungen

Diethyl tert-butylmalonate is used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide.

Bemerkungen

Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Patel, N. C.; Schwarz, J. B.; Islam, K.; Miller, W.; Tran, T. P.; Wei, Y. Improved Synthesis of gamma-Lactones from Cyclopropyl Cyanoesters. Synth. Commun. 2011, 41 (15), 2209-2215.

Huang, J. Y.; Zhuang, J. M.; Zou, Y. S. Substituent effects of accelerator on nitroxide-mediated radical polymerization. Macromol. Res. 2011, 19 (8), 757-763.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227

Combustible liquid.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1781709
Harmonized Tariff Code
2917.19
TSCA
No

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