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5272-36-6 - 3-(Trimethylsilyl)propargyl alcohol, 98+% - 3-(Trimethylsilyl)-2-propyn-1-ol - L09649 - Alfa Aesar

L09649 3-(Trimethylsilyl)propargyl alcohol, 98+%

CAS-Nummer
5272-36-6
Synonyme
3-(Trimethylsilyl)-2-propyn-1-ol

Größe Preis ($) Menge Verfügbarkeit
1g 29,60
5g 81,60
25g 313,00
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3-(Trimethylsilyl)propargyl alcohol, 98+%

MDL
MFCD00002913
EINECS
226-094-5

Chemische Eigenschaften

Formel
C6H12OSi
Molmasse
128.25
Siedepunkt
170-172°
Flammpunkt
66°(150°F)
Dichte
0.865
Brechungsindex
1.4510
Sensitivität
Moisture Sensitive
Löslichkeit
Not miscible with water.

Anwendungen

3-(Trimethylsilyl)propargyl alcohol is used as a reagent to synthesize Isbogrel, a Thromboxane A 2 (TXA 2) synthase inhibitor and also a TXA 2 receptor antagonist that has potential to treat asthma.

Bemerkungen

Moisture Sensitive. Store away from moisture and oxidizing agents. Protect from heat. Store under dry inert gas. Protect from humidity and water. Incompatible with oxidizing agents, heat and moisture.

Literaturverweise

Reduction with Sodium bis(2-methoxyethoxy)­aluminum hydride, A13292, gives stereoselectively (E)-3-TMS-2-propen-1-ol: Org. Synth. Coll., 7, 524 (1990). For titanocene dichloride-promoted hydromagnesiation reaction with isobutylmagnesium bromide, see: Org. Synth. Coll., 8, 507, (1993). See Bis(cyclopentadienyl)­titanium dichloride, A11456.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H301-H315-H319-H335

Combustible liquid. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280h-P305+P351+P338-P309-P310a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell:

Weitere Referenzen

Beilstein
1902505
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2931.90
TSCA
Yes

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