I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
Isobutylene oxide is employed as an initiator for the preparation of polyisobutylenes. It finds application in the synthesis of 1-tert-butylperoxy-2-methyl-propan-2-ol.
Reductive lithiation with the radical anion formed from Li metal and 4,4'-Di-tert-butylbiphenyl, B21470 (LDBB) is exemplified for this epoxide. The intermediate ring-opened ß-lithioalkoxide reacts with an aldehyde to give a 1,3-diol: J. Org. Chem., 55, 1528 (1990); Org. Synth. Coll., 9, 306 (1998):
Kim, S. H.; Han, S. Y.; Kim, J. H.; Kang, Y. Y.; Lee, J.; Kim, Y. Monomeric or Dimeric Aluminum Complexes as Catalysts for Cycloaddition between CO2 and Epoxides. Eur. J. Inorg. Chem. 2015, 2015 (13), 2323-2329.
Liu, C.; Yin, Q.; Dai, L. X.; You, S. L. Synthesis of pyrroloindolines and furoindolines via cascade dearomatization of indole derivatives with carbenium ion. Chem. Commun. 2015, 51 (27), 5971-5974.
Gefahrenhinweise (EU): H225-H303-H314-H318
Highly flammable liquid and vapour. May be harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.