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23356-96-9 - (S)-(+)-Prolinol, 98% - H-Pro-ol - (S)-(+)-2-Pyrrolidinemethanol - L09779 - Alfa Aesar

L09779 (S)-(+)-Prolinol, 98%

CAS-Nummer
23356-96-9
Synonyme
H-Pro-ol
(S)-(+)-2-Pyrrolidinemethanol

Größe Preis ($) Menge Verfügbarkeit
1g 29,07
5g 99,81
25g 274,45
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(S)-(+)-Prolinol, 98%

MDL
MFCD00005255
EINECS
245-605-2

Chemische Eigenschaften

Formel
C5H11NO
Molmasse
101.15
Schmelzpunkt
42-44°
Siedepunkt
74-76°/2mm
Flammpunkt
86°(186°F)
Dichte
1.025
Brechungsindex
1.4853
Sensitivität
Air Sensitive & Hygroscopic
Löslichkeit
Fully miscible in water. Soluble in chloroform.

Anwendungen

It is an active pharmaceutical intermediate.

Bemerkungen

Store at room temperature. Incompatible with strong oxidizing agents.

Literaturverweise

Shinichi Itsuno.; Koichi Ito.; Akira Hirao.; Seiichi Nakahama. Asymmetric synthesis using chirally modified borohydrides. Part 2. Enantioselective reduction of ketones with polymeric (S)-prolinol-borane reagent.J. Chem. Soc., Perkin Trans. 1. 1984, 2887-2893 .

David Alker.; Kevin J. Doyle.; Laurence M. Harwood.; Andrew McGregor. The direct synthesis of the cyclic sulphamidate of (S)-prolinol: SimultaneousN-protection and activation towards nucleophilic displacement of oxygen.Tetrahedron: Asymmetry. 1990, 1 (12),877-880 .

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H227

Causes skin irritation. Causes serious eye irritation. Combustible liquid.

Sicherheitshinweise: P210-P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
79843
Harmonized Tariff Code
2933.79
TSCA
No

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