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23356-96-9 - (S)-(+)-Prolinol, 98% - H-Pro-ol - (S)-(+)-2-Pyrrolidinemethanol - L09779 - Alfa Aesar

L09779 (S)-(+)-Prolinol, 98%

CAS-Nummer
23356-96-9
Synonyme
H-Pro-ol
(S)-(+)-2-Pyrrolidinemethanol

Größe Preis ($) Menge Verfügbarkeit
1g 29,80
5g 95,90
25g 287,00
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(S)-(+)-Prolinol, 98%

MDL
MFCD00005255
EINECS
245-605-2

Chemische Eigenschaften

Formel
C5H11NO
Molmasse
101.15
Schmelzpunkt
42-44°
Siedepunkt
74-76°/2mm
Flammpunkt
86°(186°F)
Dichte
1.025
Brechungsindex
1.4853
Sensitivität
Air Sensitive & Hygroscopic
Löslichkeit
Fully miscible in water. Soluble in chloroform.

Anwendungen

It is an active pharmaceutical intermediate.

Bemerkungen

Store at room temperature. Incompatible with strong oxidizing agents.

Literaturverweise

Shinichi Itsuno.; Koichi Ito.; Akira Hirao.; Seiichi Nakahama. Asymmetric synthesis using chirally modified borohydrides. Part 2. Enantioselective reduction of ketones with polymeric (S)-prolinol-borane reagent.J. Chem. Soc., Perkin Trans. 1. 1984, 2887-2893 .

David Alker.; Kevin J. Doyle.; Laurence M. Harwood.; Andrew McGregor. The direct synthesis of the cyclic sulphamidate of (S)-prolinol: SimultaneousN-protection and activation towards nucleophilic displacement of oxygen.Tetrahedron: Asymmetry. 1990, 1 (12),877-880 .

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H315-H319

Combustible liquid. Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
79843
Harmonized Tariff Code
2933.79
TSCA
No

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