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L10742 1-Chloro-2-iodoethane, 96%, stab. with copper

CAS-Nummer
624-70-4
Synonyme
Ethylene chloroiodide

Stock No. Größe Preis ($) Menge Verfügbarkeit
L10742-03 1g 32,90
L10742-06 5g 111,00
L10742-14 25g 430,00
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1-Chloro-2-iodoethane, 96%, stab. with copper

MDL
MFCD00041453
EINECS
677-827-4

Chemische Eigenschaften

Formel
C2H4ClI
Molmasse
190.41
Siedepunkt
61-62°/30mm
Flammpunkt
>100°(212°F)
Dichte
2.088
Brechungsindex
1.5660
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Löslichkeit
Soluble inorganic solvents. Insoluble in water.

Anwendungen

1-Chloro-2-iodoethane is used as a mild electrophile for iodination of metallated species, as in the conversion of an ortho-lithiated benzyl ether to the corresponding ortho-iodide. It reacts with 5-hydroxy-[1,4]naphthoquinone, and obtain the 5-(2-chloro-ethoxy)-[1,4]naphthoquinone.

Bemerkungen

Incompatible with strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

Xuming Zheng.; David Lee Phillips. A-band resonance Raman spectra and short-time photodissociation dynamics of trans 1-chloro-2-iodoethane in cyclohexane solution. Chemical Physics Letters. 1998, 286 (1-2), 79-87.

Xuming Zheng.; David Lee Phillips. Investigation of the short-time photodissociation dynamics of trans-1-bromo-2-iodoethane in the A -band absorption. J. Chem. Phys. 1999, 110 1638 .

Mild electrophile for iodination of metallated species, as in the conversion of an ortho-lithiated benzyl ether to the corresponding ortho-iodide: J. Chem. Soc., Chem. Commun., 124 (1979); J. Org. Chem., 47, 2541 (1982); J. Chem. Soc., Perkin 1, 115 (1985). See also 1,2-Diiodoethane, L03019.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302

Harmful if swallowed.

Sicherheitshinweise: P264-P270-P301+P312a-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1730865
Harmonized Tariff Code
2903.79
TSCA
No

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