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590-90-9 - 4-Hydroxy-2-butanone, 95% - L11456 - Alfa Aesar

L11456 4-Hydroxy-2-butanone, 95%

CAS-Nummer
590-90-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25g 43,20
100g 111,00
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4-Hydroxy-2-butanone, 95%

MDL
MFCD00059005
EINECS
209-693-6

Chemische Eigenschaften

Formel
C4H8O2
Molmasse
88.11
Siedepunkt
73-76°/12mm
Flammpunkt
89°(192°F)
Dichte
1.020
Brechungsindex
1.4310
Löslichkeit
Miscible with water, alcohol, ethanol and ether.

Anwendungen

4-Hydroxy-2-butanone is used in the preparation of fused benzazepine molecules as selective D3 receptor antagonists with pharmaceutical activity. It is also used in the preparation of verrucarin and mevalonic acid lactone. Further, it is used to prepare 3-buten-2-one through dehydration over an anatase titanium dioxide catalyst. It is also employed in the preparation of 4-methyl-5-hydroxymethylthiazole, (±)-lineatin and beta-hydroxylactones.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Mei, J.; Mao, J.; Chen, Z.; Yuan, S.; Li, H.; Yin, H. Mechanism and kinetics of 4-hydroxy-2-butanone formation from formaldehyde and acetone under supercritical conditions and in high-temperature liquid-phase. Chem. Eng. Sci. 2015, 131, 213-218.

Bouzidi, H.; Aslan, L.; El Dib, G.; Coddeville, P.; Fittschen, C.; Tomas, A. Investigation of the Gas-Phase Photolysis and Temperature-Dependent OH Reaction Kinetics of 4-Hydroxy-2-butanone. Environ. Sci. Technol. 2015, 49 (20), 12178-12186.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Sicherheitshinweise: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1737666
Harmonized Tariff Code
2914.40
TSCA
Yes

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