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1707-77-3 - 1,2:5,6-Di-O-isopropylidene-D-mannitol - 1,2:5,6-Diacetone-D-mannitol - L12127 - Alfa Aesar

L12127 1,2:5,6-Di-O-isopropylidene-D-mannitol

CAS-Nummer
1707-77-3
Synonyme
1,2:5,6-Diacetone-D-mannitol

Größe Preis ($) Menge Verfügbarkeit
5g 40,50
25g 143,00
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1,2:5,6-Di-O-isopropylidene-D-mannitol

MDL
MFCD00003211
EINECS
216-954-8

Chemische Eigenschaften

Formel
C12H22O6
Molmasse
262.31
Schmelzpunkt
120-122°

Literaturverweise

Treatment with NaIO 4 affords the useful synthon 2,3-O-isopropylidene-D-glyceraldehyde (glyceraldehyde acetonide): J. Org. Chem., 56, 4056 (1991); Org. Synth. Coll., 9, 450 (1998). This in turn can be homologated diastereoselectively using 2-(Trimethyl­silyl)­thiazole, B21903: Org. Synth. Coll., 9, 52 (1998). For use of Pb(OAc) 4 in the formation of glyceraldehyde acetonide as a chiral precursor of cyclopropyl carbocyclic nucleosides as HIV reverse transcriptase inhibitors, see: J. Org. Chem., 60, 5236 (1995).

/n

GHS Gefahren- und Sicherheitshinweise

Sicherheitshinweise: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
83765
Harmonized Tariff Code
2932.99
TSCA
No

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