Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

2531-80-8 - Ethyl 2-nitropropionate, 96% - 2-Nitropropionic acid ethyl ester - L12261 - Alfa Aesar

L12261 Ethyl 2-nitropropionate, 96%

CAS-Nummer
2531-80-8
Synonyme
2-Nitropropionic acid ethyl ester

Größe Preis ($) Menge Verfügbarkeit
1g 22,45
5g 85,77
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Ethyl 2-nitropropionate, 96%

MDL
MFCD00024818

Chemische Eigenschaften

Formel
C5H9NO4
Molmasse
147.13
Siedepunkt
190-195°
Flammpunkt
89°(192°F)
Dichte
1.130
Brechungsindex
1.4210
Löslichkeit
Not miscible in water.

Anwendungen

Ethyl 2-nitropropionate is used in the preparation of (-)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst, novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion, 2-ethoxycarbonyl-2-nitropentanal. It is used for enantioselective Michael reactions.

Bemerkungen

Incompatible with oxidizing agents. Store in a cool, dry conditions in well sealed container.

Literaturverweise

Jeremy R Duvall; Fanghui Wu; Barry B Snider. Structure reassignment and synthesis of Jenamidines A1/A2, synthesis of (+)-NP25302, and formal synthesis of SB-311009 analogues. J. Org. Chem.2006, 71, (22), 8579-8590.

H Zhang; J Joseph; J Vasquez-Vivar; H Karoui; C Nsanzumuhire; P Martásek; P Tordo; B Kalyanaraman. FEBS Letters.2000, 473, (1), 58-62.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Sicherheitshinweise: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
774734
Harmonized Tariff Code
2915.90
TSCA
Yes

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf