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5518-52-5 - Tri(2-furyl)phosphine, 97% - Tris(2-furyl)phosphine - L13329 - Alfa Aesar

L13329 Tri(2-furyl)phosphine, 97%

CAS-Nummer
5518-52-5
Synonyme
Tris(2-furyl)phosphine

Größe Preis ($) Menge Verfügbarkeit
250mg 25,04
1g 67,36
5g 210,52
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Tri(2-furyl)phosphine, 97%

MDL
MFCD00151857
EINECS
000-000-0

Chemische Eigenschaften

Formel
C12H9O3P
Molmasse
232.18
Schmelzpunkt
59-64°
Siedepunkt
136°/4mm

Literaturverweise

Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).

/n

Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).

/n

In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1577564
Harmonized Tariff Code
2932.19
TSCA
No

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