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N-Methylaniline is used in the preparation of N,N'-dimethylsulfinyldianilin using triethylamine and thionyl chloride as reagents. It is also acts as a latent and coupling solvent. Further, it serves as an intermediate for dyes and agrochemicals. In addition to this, it is utilized as an antiknock agent, which plays an essential role to increase the octane number.
N-Alkylanilines react with triethanolamine in dioxan (autoclave) in the presence of Dichlorotris(triphenylphosphine)ruthenium(II), L00373, to give the corresponding 1-alkylindole in good yield: Synth. Commun., 26, 1349 (1996).
Emelyanenko, V. N.; Pimerzin, A. A.; Turovtsev, V. V.; Verevkin, S. P. Benchmark Thermochemistry of N-Methylaniline. J. Phys. Chem. A 2015, 119 (10), 2142-2152.
Belyaeva, E. I.; Zrelova, L. V.; Marchenko, D. Y.; Dedov, A. G. Colorimetric determination of N-methylaniline in hydrocarbon media. Petro. Chem. 2015, 55 (1), 74-79.
Gefahrenhinweise (EU): H227-H301-H311-H331-H373
Combustible liquid. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.