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20439-47-8 - (1R,2R)-(-)-1,2-Diaminocyclohexane, 98% - (1R)-trans-1,2-Cyclohexanediamine - L14059 - Alfa Aesar

L14059 (1R,2R)-(-)-1,2-Diaminocyclohexane, 98%

CAS-Nummer
20439-47-8
Synonyme
(1R)-trans-1,2-Cyclohexanediamine

Größe Preis ($) Menge Verfügbarkeit
250mg 23,40
1g 59,60
5g 195,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(1R,2R)-(-)-1,2-Diaminocyclohexane, 98%

MDL
MFCD00062985

Chemische Eigenschaften

Formel
C6H14N2
Molmasse
114.19
Schmelzpunkt
40-43°
Siedepunkt
104-110°/40mm
Flammpunkt
70°(158°F)
Sensitivität
Air Sensitive
Löslichkeit
Soluble in water.

Anwendungen

(1R,2R)-(-)-1,2-Diaminocyclohexane is a versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.

Bemerkungen

Air sensitive. Store under inert gas. Store away from oxidizing agents, air, carbondioxide.

Literaturverweise

Catherine Bied; Joël J.E. Moreau; Michel Wong Chi Man. Chiral amino-urea derivatives of (1R,2R)-1,2-diaminocyclohexane as ligands in the ruthenium catalysed asymmetric reduction of aromatic ketones by hydride transfer. Tetrahedron: Asymmetry. 2001, 12, (2), 329-336.

M. Kaik; J. Gawroński. Facile monoprotection of trans-1,2-diaminocyclohexane. Tetrahedron: Asymmetry. 2003, 14, (11), 1559-1563.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318-H317

Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction.

Sicherheitshinweise: P262-P280-P305+P351+P338-P309-P310a

Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell:

Weitere Referenzen

Beilstein
4780911
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2921.30
TSCA
No

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