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(1R,2R)-(-)-1,2-Diaminocyclohexane is a versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.
Catherine Bied; Joël J.E. Moreau; Michel Wong Chi Man. Chiral amino-urea derivatives of (1R,2R)-1,2-diaminocyclohexane as ligands in the ruthenium catalysed asymmetric reduction of aromatic ketones by hydride transfer. Tetrahedron: Asymmetry. 2001, 12, (2), 329-336.
M. Kaik; J. Gawroński. Facile monoprotection of trans-1,2-diaminocyclohexane. Tetrahedron: Asymmetry. 2003, 14, (11), 1559-1563.
Gefahrenhinweise (EU): H314-H318-H317
Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction.
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