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2873-29-2 - 3,4,6-Tri-O-acetyl-D-glucal, 98% - 1,2-Dideoxy-3,4,6-tri-O-acetyl-D-arabino-1-hexenopyranose - L14103 - Alfa Aesar

L14103 3,4,6-Tri-O-acetyl-D-glucal, 98%

CAS-Nummer
2873-29-2
Synonyme
1,2-Dideoxy-3,4,6-tri-O-acetyl-D-arabino-1-hexenopyranose

Größe Preis ($) Menge Verfügbarkeit
5g 23,59
25g 69,73
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

3,4,6-Tri-O-acetyl-D-glucal, 98%

MDL
MFCD00063253
EINECS
220-709-0

Chemische Eigenschaften

Formel
C12H16O7
Molmasse
272.26
Schmelzpunkt
52-55°
Löslichkeit
Soluble in chloroform and ethanol. Insoluble in water.

Anwendungen

3,4,6-Tri-O-acetyl-D-glucal acts as a building block for the synthesis of oligosaccharides in both solution and solid-phase. Further, it is used in the preparation of D-arabino-1,5-anhydro-2-deoxy-hex-1-enitol.

Bemerkungen

Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong acids.

Literaturverweise

Chen, P.; Bi, B. Preparation of 2,3-unsaturated pseudoglycosides with Ferrier Rearrangement promoted by Tm(OTf)3 as a highly efficient catalyst. Tetrahedron Lett. 2015, 56 (34), 4895-4899.

Mirabella, S.; Cardona, F.; Goti, A. Osmium-Catalyzed Tethered Aminohydroxylation of Glycals: A Stereodirected Access to 2- and 3-Aminosugars. Org. Lett. 2015, 17 (3), 728-731.

Weitere Referenzen

Beilstein
90781
Harmonized Tariff Code
2940.00
TSCA
No

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