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3976-69-0 - Methyl (R)-(-)-3-hydroxybutyrate, 98% - (R)-(-)-3-Hydroxybutyric acid methyl ester - L14151 - Alfa Aesar

L14151 Methyl (R)-(-)-3-hydroxybutyrate, 98%

CAS-Nummer
3976-69-0
Synonyme
(R)-(-)-3-Hydroxybutyric acid methyl ester

Größe Preis ($) Menge Verfügbarkeit
1g 28,40
5g 82,70
25g 282,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Methyl (R)-(-)-3-hydroxybutyrate, 98%

MDL
MFCD00063289
EINECS
223-610-0

Chemische Eigenschaften

Formel
C5H10O3
Molmasse
118.13
Siedepunkt
56-58°/11mm
Flammpunkt
73°(163°F)
Dichte
1.055
Brechungsindex
1.4220
Löslichkeit
Slightly soluble in water.

Anwendungen

Can undergo aldol-type reactions with aldehydes with either syn- or anti-selectivity according to the conditions, for use in the synthesis of chiral ß-lactams.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literaturverweise

Xiao-Hong Chen; Ping Wei; Xiao-Ting Wang; Min-Hua Zong; Wen-Yong Lou. A novel carbonyl reductase with anti-Prelog stereospecificity from Acetobacter sp. CCTCC M209061: purification and characterization. PLoS ONE. 2014, 9, (4), e94543.

Bezhan Chankvetadze; Mayuko Saito; Eiji Yashima and Yoshio Okamoto. Enantioseparation of atropisomeric 1,1?-binaphthyl-2,2?-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis. Chirality. 1998, 10, (1-2), 134-139.

For use in the synthesis of chiral ß-lactams, see: J. Chem. Soc., Chem. Commun., 1376 (1988).

Can undergo aldol-type reactions with aldehydes with either syn- or anti-selectivity according to the conditions: Chem. Lett., 1931 (1990).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H315-H318

Combustible liquid. Causes skin irritation. Causes serious eye damage.

Sicherheitshinweise: P210-P280b-P305+P351+P338-P310a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
3648161
Harmonized Tariff Code
2918.19
TSCA
No

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