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557-93-7 - 2-Bromopropene, 99%, stab. - Isopropenyl bromide - L14229 - Alfa Aesar

L14229 2-Bromopropene, 99%, stab.

CAS-Nummer
557-93-7
Synonyme
Isopropenyl bromide

Größe Preis ($) Menge Verfügbarkeit
5g 41,00
25g 137,00
100g 378,00
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2-Bromopropene, 99%, stab.

MDL
MFCD00000140
EINECS
209-185-4

Chemische Eigenschaften

Formel
C3H5Br
Molmasse
120.98
Schmelzpunkt
-87°
Siedepunkt
47-49°
Flammpunkt
4°(39°F)
Dichte
1.362
Brechungsindex
1.4430
Sensitivität
Light Sensitive
Löslichkeit
Immiscible with water.

Anwendungen

2-Bromopropene is used as a solvent and as an intermediate for organic synthesis. It is also used as a fumigant. Further, it reacts with nonanal to prepare 2-methyl-undec-1-en-3-ol using chromium(II) chloride as a reagent. It is utilized as a refrigerant used in organic synthesis.

Bemerkungen

Light sensitive. Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Bracco, L. L. B.; Badenes, M. P.; Tucceri, M. E.; Cobos, C. J. Theoretical kinetic study of the unimolecular decomposition of 2-bromopropene. Chem. Phys. Lett. 2014, 608, 386-392.

Vila, C.; Giannerini, M.; Hornillos, V.; Fañanás-Mastral, M.; Feringa, B. L. Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents. Chem. Sci. 2014, 5 (4), 1361-1367.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1731926
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
UC7085000

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