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(R)-(-)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride is used as a chiral acylating reagent, which is used in the resolution of amino acid enantiomers like 2,5-dimethoxy-4-methylamphetamine. It is also suitable for the determination of the optical composition of compounds extracted from biological fluids.
Chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines by NMR: J. Am. Chem. Soc., 95, 512 (1973)./n
Hasegawa, H.; Shinohara, Y.; Masuda, N.; Hashimoto, T.; Ichida, K. Simultaneous determination of serine enantiomers in plasma using Mosher's reagent and stable isotope dilution gas chromatography-mass spectrometry. J. Mass Spectrom. 2011, 46 (5), 502-507.
Chavda, S.; Coulbeck, E.; Dingjan, M.; Eames, J.; Motevalli, M. Probing the parallel resolution of Moshers acid using a combination of quasi-enantiomeric oxazolidin-2-ones. Tetrahedron: Asymmetry 2008, 19 (10), 1274-1284.
Gefahrenhinweise (EU): H227-H314-H318
Combustible liquid. Causes severe skin burns and eye damage. Causes serious eye damage.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.