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128143-89-5 - 4'-Chloro-2,2':6',2''-terpyridine, 98% - L14728 - Alfa Aesar

L14728 4'-Chloro-2,2':6',2''-terpyridine, 98%

CAS-Nummer
128143-89-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
250mg 41,41
1g 100,63
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4'-Chloro-2,2':6',2''-terpyridine, 98%

MDL
MFCD00191930

Chemische Eigenschaften

Formel
C15H10ClN3
Molmasse
267.72
Schmelzpunkt
148-152°
Löslichkeit
Slightly soluble in water.

Anwendungen

4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).

Bemerkungen

Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literaturverweise

Zhang, G.; Tan, J.; Zhang, Y. Z.; Ta, C.; Sanchez, S.; Cheng, S. Y.; Golen, J. A.; Rheingold, A. L. Syntheses, structures and cytotoxicity of cobalt(II) complexes with 4'-chloro-2,2':6',2?-terpyridine. Inorg. Chim. Acta 2015, 435, 147-152.

Saghatforoush, L. A.; Valencia, L.; Chalabian, F.; Ghammamy, S.; Khaledi, L. Z. Synthesis, crystal structure, and biological activity of 4'-chloro-2,2'?:?6',2?-terpyridine (Cltpy) as tridentate ligand in a Cd(II) complex. J. Coord. Chem. 2011, 64 (19), 3311-3322.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
3613386
Harmonized Tariff Code
2933.39
TSCA
No

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