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Reducing agent for the preparation of plate-type palladium-zinc oxide catalys, reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents. Catalyst for regioselective reductive opening of benzylidene acetal glycosides and polarity reversal.
Alessandro D'Ulivo; Valeria Loreti; Massimo Onor; Emanuela Pitzalis; Roberto Zamboni. Chemical vapor generation atomic spectrometry using amineboranes and cyanotrihydroborate(III) reagents. Analytical chemistry.2003, 75,(11), 2591-2600.
Andrei A. Sherman et. al. The presence of water improves reductive openings of benzylidene acetals with trimethylaminoborane and aluminum chloride. Carbohydrate Research,.2003, 338(8), 697-703.
Selective reducing agent. Reactivity in carbonyl reductions is promoted by protic or Lewis acids: J. Am. Chem. Soc., 86, 3882 (1964). In the presence of HCl, indoles are reduced to indolines: Synthesis, 508 (1974). For a review of amine boranes, see: Org. Prep. Proced. Int., 16, 335 (1984).
Gefahrenhinweise (EU): H228-H315-H319-H335
Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.