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7397-46-8 - Diethylmethoxyborane, 1M soln in THF - L15107 - Alfa Aesar

L15107 Diethylmethoxyborane, 1M soln in THF

CAS-Nummer
7397-46-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25ml 33,06
100ml 76,53
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Diethylmethoxyborane, 1M soln in THF

MDL
MFCD00013240

Chemische Eigenschaften

Formel
C5H13BO
Molmasse
99.97
Flammpunkt
-6°(21°F)
Dichte
0.868
Brechungsindex
1.4040
Sensitivität
Air & Moisture Sensitive

Literaturverweise

Has been used in combination with sodium borohydride for selective reductions: ß-hydroxy ketones are reduced with high diastereoselectivity to syn-diols: Tetrahedron Lett., 28, 155 (1987); ß δ-diketo esters are reduced to ß δ-dihydroxy esters without reduction of a conjugated olefinic double bond: Tetrahedron Lett., 29, 6467 (1988).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H351-H373-H317-H335-H303-H333

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause an allergic skin reaction. May cause respiratory irritation. May be harmful if swallowed. May be harmful if inhaled.

Sicherheitshinweise: P210-P260-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2231225
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
ED6151000

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