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Has been used in combination with sodium borohydride for selective reductions: ß-hydroxy ketones are reduced with high diastereoselectivity to syn-diols: Tetrahedron Lett., 28, 155 (1987); ß δ-diketo esters are reduced to ß δ-dihydroxy esters without reduction of a conjugated olefinic double bond: Tetrahedron Lett., 29, 6467 (1988)./n
Gefahrenhinweise (EU): H225-H302-H333-H314-H318-H317-H351-H335-H373
Highly flammable liquid and vapour. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.