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4856-95-5 - Borane-morpholine complex, 97% - Morpholine borane - L15110 - Alfa Aesar

L15110 Borane-morpholine complex, 97%

CAS-Nummer
4856-95-5
Synonyme
Morpholine borane

Größe Preis ($) Menge Verfügbarkeit
5g 22,04
25g 60,93
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Borane-morpholine complex, 97%

MDL
MFCD00066736
EINECS
225-450-7

Chemische Eigenschaften

Formel
C4H12BNO
Molmasse
100.96
Schmelzpunkt
93-95°

Literaturverweise

Selective reducing agent. Reactivity in carbonyl reductions is increased in acidic media: J. Am. Chem. Soc., 92, 4203 (1970); J. Chem. Soc., Perkin 2, 1948 (1973). For a review of amine boranes as selective reducing and hydroborating agents, see: Org. Prep. Proced. Int., 16, 335 (1984).

/n

Treatment with n-BuLi generates the lithium aminoborohydride, a powerful reducing agent similar to LiAH4 in its reducing power, but air-stable and non-pyrophoric: J. Org. Chem., 59, 6378 (1994).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H228-H314-H318-H302

Flammable solid. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
4.1
Verpackungsgruppe
II
Harmonized Tariff Code
2934.99
TSCA
Yes
RTECS
QD8530000

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