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14593-46-5 - Sodium tert-pentyloxide, 95% - Sodium tert-amylate - Sodium 2-methyl-2-butoxide - L15112 - Alfa Aesar

L15112 Sodium tert-pentyloxide, 95%

CAS-Nummer
14593-46-5
Synonyme
Sodium tert-amylate
Sodium 2-methyl-2-butoxide

Größe Preis ($) Menge Verfügbarkeit
25g 27,00
100g 52,70
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Sodium tert-pentyloxide, 95%

MDL
MFCD00064245
EINECS
238-369-4

Chemische Eigenschaften

Formel
C5H11NaO
Molmasse
110.13
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Reacts with water.

Anwendungen

Sodium tert-pentyloxide is a effective base for the alkylation of ketones.

Bemerkungen

Air and Moisture Sensitive, store away form air and water/moisture. Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

I. N. Nazarov; S. N. Ananchenko; I. V. Torgov. Condensation of 1-vinylcyclohexene with propiolic and tetrolic acids and esters. Bulletin of the Academy of Sciences of the USSR, Division of chemical science.1959, 8,(1), 84-90.

Strong, hydrocarbon-soluble base: J. Organomet. Chem., 364, 281 (1989). Useful base for the Wittig reaction: Tetrahedron Lett., 31, 635 (1990).

In combination with LDA forms a 'superbasic ' reagent: Synthesis, 1493 (1995).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H251-H228-H314-H318

Self-heating: may catch fire. Flammable solid. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
3983987
Gefahrenklasse
4.2
Verpackungsgruppe
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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