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N-Methyldiethanolamine is a reagent used for protection of boronic acids as N-methyl-O,O-diethanolamine esters.
Edward B. Rinker.; S.Ashour Sami.; Orville C. Sandall. Edward B. Rinker, S.Ashour Sami, Orville C. Sandall. Kinetics and modelling of carbon dioxide absorption into aqueous solutions of N-methyldiethanolamineChemical Engineering Science. 1995, 50 (5), 755-768.
Daniel P. Hagewiesche, Sami S. Ashour, Hani A. Al-Ghawas, Orville C. Sandall. Absorption of carbon dioxide into aqueous blends of monoethanolamine and N-methyldiethanolamine. Chemical Engineering Science. 1995, 50 (7), 1071-10795.
Reagent for protection of boronic acids as N-methyl-O,O-diethanolamine esters (cf Diethanolamine, A13389). The resulting derivatives have been converted to fluoroaromatics using cesium fluoroxysulfate: Synlett, 761 (1990); Tetrahedron, 48, 8073 (1992).
The boronic esters are also stable in the presence of organometallic (e.g. lithium derivatives): J. Org. Chem., 54, 4734 (1989).
Gefahrenhinweise (EU): H319
Causes serious eye irritation.
Wear eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.