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13199-25-2 - 2,3-O-Isopropylidene-alpha,beta-D-ribofuranose - L15988 - Alfa Aesar

L15988 2,3-O-Isopropylidene-alpha,beta-D-ribofuranose

CAS-Nummer
13199-25-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 69,70
5g 278,00
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2,3-O-Isopropylidene-alpha,beta-D-ribofuranose

MDL
MFCD01075718

Chemische Eigenschaften

Formel
C8H14O5
Molmasse
190.20
Löslichkeit
Soluble in acetone.

Anwendungen

2,3-O-Isopropylidene-alpha,beta-D-ribofuranose is used as a pharmaceutical intermediate.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

Literaturverweise

J.Grant Buchanan, Allan D. Dunn, Alan R. Edgar. Reaction of ethynylmagnesium bromide with 2,3-O-isopropylidene-D-ribose and 2,3:5,6-di-O-isopropylidene-D-mannofuranose: syntheses of glycofuranosylethynes. Carbohydrate Research. 1974, 36 (1), C5-C7.

N.A. Hughes.; P.R.H. Speakman. New isopropylidene derivatives of d-ribose: 1,2:3,4-di-O-isopropylidene-d-ribopyranose and 1,2-O-isopropylidene-d-ribopyranose. Carbohydrate Research. 1965, 1 (2), 171-175.

Reaction of this hemiacetal with various organometallic species provides routes to a number of synthetic targets, e.g.: (-)-5-epishikimic acid: Tetrahedron Lett., 35, 5505 (1994); J. Chem. Soc., Perkin 1, 1805 (1997), aminocyclopentitols: Tetrahedron: Asymmetry, 6, 1547 (1995), cyclopentane-type glycosidase inhibitors: J. Org. Chem., 61, 1354 (1996). Reaction with cysteamine leads to diastereomerically pure analogues of the alkaloids castanospermine and australine: Tetrahedron Lett., 37, 49 (1996).

Weitere Referenzen

Harmonized Tariff Code
2932.99
TSCA
No

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Metalle und Stoffe

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