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290-87-9 - 1,3,5-Triazine, 97% - s-Triazine - L16911 - Alfa Aesar

L16911 1,3,5-Triazine, 97%

CAS-Nummer
290-87-9
Synonyme
s-Triazine

Größe Preis ($) Menge Verfügbarkeit
1g 35,43
5g 100,80
25g 295,61
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

1,3,5-Triazine, 97%

MDL
MFCD00006044
EINECS
206-028-1

Chemische Eigenschaften

Formel
C3H3N3
Molmasse
81.08
Schmelzpunkt
77-83° dec.
Siedepunkt
114°
Dichte
1.380
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in ethanol (50 mg/ml), and methanol (100 mg/ml).

Anwendungen

1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature. Store under dry inert gas.

Literaturverweise

N. G. McCormick.; J. H. Cornell.; A. M. Kaplan. Biodegradation of Hexahydro-1,3,5-Trinitro-1,3,5-Triazine. Appl. Environ. Microbiol.. 1981, 42 (5), 817-823.

Francis H. Case.; Emil Koft. The Synthesis of Certain Substituted 1,3,5-Triazines Containing the Ferroin Group. J. Am. Chem. Soc. 1959, 81 (4), 905-906.

Formylating agent: useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes: J. Am. Chem. Soc., 76, 290 (1954); Angew. Chem. Int. Ed., 6, 940 (1969); Arch. Pharm., 302, 828 (1969); 304, 362 (1971); with reactive substrates, formylation can be accomplished without a catalyst.

Also reacts with nucleophiles, e.g. amines, which has been utilized in a quinazoline synthesis: J. Chem. Soc. (C), 1282 (1969):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H318-H315-H302-H335

Causes serious eye damage. Causes skin irritation. Harmful if swallowed. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P310-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
104790
Harmonized Tariff Code
2933.69
TSCA
No
RTECS
XY2957000

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