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23357-46-2 - (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 98+% - (R)-1-Amino-1,2,3,4-tetrahydronaphthalene - L17021 - Alfa Aesar

L17021 (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 98+%

CAS-Nummer
23357-46-2
Synonyme
(R)-1-Amino-1,2,3,4-tetrahydronaphthalene

Größe Preis ($) Menge Verfügbarkeit
1g 31,00
5g 76,10
25g 255,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine, ChiPros® 99+%, ee 98+%

MDL
MFCD00671629
EINECS
000-000-0

Chemische Eigenschaften

Formel
C10H13N
Molmasse
147.22
Siedepunkt
118-120°/8mm
Flammpunkt
>110°(230°F)
Dichte
1.035
Brechungsindex
1.5645
Sensitivität
Air Sensitive
Löslichkeit
Soluble in water (6.91g/L at 25°C).

Anwendungen

(R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks or chiral auxiliaries.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with oxidizing agents.

Literaturverweise

Min Qiu.; Xiang-Ping Hu.; Jia-Di Huang.; Dao-Yong Wang.; Jun Deng.; Sai-Bo Yu.; Zheng-Chao Duan.; Zhuo Zheng. Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations. Advanced Synthesis & Catalysis. 2008, 350 (17), 2683-2689.

Min Qiu.; Xiang-Ping Hu.; Dao-Yong Wang.; Jun Deng.; Jia-Di Huang.; Sai-Bo Yu.; Zheng-Chao Duan.; Zhuo Zheng. Chiral 1,2,3,4-Tetrahydro-1-naphthylamine-Derived Phosphine-Phosphoramidite Ligand (THNAPhos): Application in Highly Enantioselective Hydrogenations of Functionalized C[DOUBLE BOND]C Bonds. Langmuir. 2008, 350 (9), 1413-1418.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
4231302
Harmonized Tariff Code
2921.45
TSCA
No

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