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16518-62-0 - 3-Bromo-N,N-dimethylaniline, 97% - L17279 - Alfa Aesar

L17279 3-Bromo-N,N-dimethylaniline, 97%

CAS-Nummer
16518-62-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 61,49
25g 243,08
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3-Bromo-N,N-dimethylaniline, 97%

MDL
MFCD00045020
EINECS
000-000-0

Chemische Eigenschaften

Formel
C8H10BrN
Molmasse
200.08
Schmelzpunkt
11°
Siedepunkt
126°/14mm
Dichte
1.365
Brechungsindex
1.6015
Löslichkeit
Miscible with chloroform, dichloromethane and methanol.

Anwendungen

3-Bromo-N,N-dimethylaniline is involved in fluorination using metal fluoride in the presence of 2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl (AdBrettPhos)-based Pd precatalyst, used to prepare 3-fluoro-N,N- dimethylaniline.

Bemerkungen

Light sensitive. Store in cool place. Incompatible with strong oxidizing agents and strong acids.

Literaturverweise

Sursvakova, V. V.; Burmakina, G. V.; Rubaylo, A. I. Palladium-Catalyzed Oxidative Carbonylation of Aromatic C-H Bonds of N-Alkylanilines with CO and Alcohols for the Synthesis of o-Aminobenzoates. J. Org. Chem. 2015, 80 (2), 1258-1263.

Ding, Q.; Zhou, X.; Pu, S.; Cao, B. Rhodium-catalyzed ortho-selective C-H halogenation of 2-arylbenzo[d]thiazoles using N-halosuccinimides as halogen sources. Tetrahedron 2015, 71 (16), 2376-2381.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H332-H315-H319

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2079908
Harmonized Tariff Code
2921.42
TSCA
No

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