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Boron trifluoride-tetrahydrofuran complex is used as a polymerization initiator and as a dopant in the semiconductor industry. It serves as a reagent for deoxofluorination of alcohols and carbonyls. Further, it is used in the synthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytes and hydroboration-oxidation of divinylferrocene. In addition to this, it is used as a reagent for the preparation of NK1 receptor antagonists, complex polyketide natural products and selective serotonin reuptake inhibitors.
Gong, W.; Jin, B.; Peng, R.; Deng, N.; Zheng, R.; Chu, S. Synthesis and Characterization of Fullerene-Poly(glycidyl nitrate) and Its Thermal Decomposition. Ind. Eng. Chem. Res. 2015, 54 (10), 2613-2618.
Barrett, T. N.; Patel, B. H.; Barrett, A. G. M. Synthesis of C-5-substituted resorcylates and resorcinamides via formylation-aromatization of functionalized keto-dioxinones. Tetrahedron 2014, 70 (38), 6894-6901.
Gefahrenhinweise (EU): H227-H332-H314-H318-H372
Combustible liquid. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs through prolonged or repeated exposure.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.