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Boron trifluoride-tetrahydrofuran complex is used as a polymerization initiator and as a dopant in the semiconductor industry. It serves as a reagent for deoxofluorination of alcohols and carbonyls. Further, it is used in the synthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytes and hydroboration-oxidation of divinylferrocene. In addition to this, it is used as a reagent for the preparation of NK1 receptor antagonists, complex polyketide natural products and selective serotonin reuptake inhibitors.
Gong, W.; Jin, B.; Peng, R.; Deng, N.; Zheng, R.; Chu, S. Synthesis and Characterization of Fullerene-Poly(glycidyl nitrate) and Its Thermal Decomposition. Ind. Eng. Chem. Res. 2015, 54 (10), 2613-2618.
Barrett, T. N.; Patel, B. H.; Barrett, A. G. M. Synthesis of C-5-substituted resorcylates and resorcinamides via formylation-aromatization of functionalized keto-dioxinones. Tetrahedron 2014, 70 (38), 6894-6901.
Gefahrenhinweise (EU): H227-H332-H314-H318-H372
Combustible liquid. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs through prolonged or repeated exposure.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.