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162241-33-0 - 1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), ca 45-50% w/w on alumina - AccuFluor NFTh - L17628 - Alfa Aesar

L17628 1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), ca 45-50% w/w on alumina

CAS-Nummer
162241-33-0
Synonyme
AccuFluor NFTh

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1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate), ca 45-50% w/w on alumina

MDL
MFCD00467883
EINECS
418-330-2

Chemische Eigenschaften

Formel
C6H13B2F9N2O
Molmasse
321.79

Literaturverweise

AccuFluor is a registered trademark of AlliedSignal Inc.

/n

Versatile, reactive electrophilic fluorinating agent which can be used in water or organic solvents. A variety of substrates such as ketones: Tetrahedron Lett., 37, 3591 (1996), aromatics and enol ethers or enol esters, including steroidal derivatives, can be fluorinated successfully under mild conditions: Tetrahedron Lett., 40, 2673 (1999):

/n

Active methylene compounds (ß-diketonesandß-keto esters) are fluorinated in good yield in the presence of zinc chloride and imidazole or collidine. In the presence of water or alcohols, alkenes undergo hydroxy- or alkoxyfluorination to give fluorohydrin derivatives: Tetrahedron Lett., 36, 6769 (1995); 40, 2673 (1999).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H318-H373-H302-H317-H411-H401

Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure. Harmful if swallowed. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. Toxic to aquatic life.

Sicherheitshinweise: P260-P261-P273-P280-P305+P351+P338-P310-P301+P312-P363-P321-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Specific treatment (see label). Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
8369351
Gefahrenklasse
9
Verpackungsgruppe
III
Harmonized Tariff Code
2933.99
TSCA
No

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