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Boronation reagent, cf Bis(pinacolato)diboron, L16088, which undergoes Pd-catalyzed coupling with aryl halides to give neopentylato boronic esters, more readily hydrolyzed to boronic acids than the corresponding pinacolato esters: Chem. Abs., 129, 290220 (1998). Found to be much more efficient than bis(pinacolato)diboron for the synthesis of hindered ortho-substituted arylboronic acids: Tetrahedron Lett., 46, 1671 (2005)./n
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.