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55289-06-0 - 3-Methoxy-2-methylbenzoic acid, 97% - 3-Methoxy-o-toluic acid - 2-Methyl-m-anisic acid - L18729 - Alfa Aesar

L18729 3-Methoxy-2-methylbenzoic acid, 97%

CAS-Nummer
55289-06-0
Synonyme
3-Methoxy-o-toluic acid
2-Methyl-m-anisic acid

Größe Preis ($) Menge Verfügbarkeit
10g 43,90
50g 142,00
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3-Methoxy-2-methylbenzoic acid, 97%

MDL
MFCD02094039

Chemische Eigenschaften

Formel
C9H10O3
Molmasse
166.18
Löslichkeit
Soluble in methanol. Insoluble in water.

Anwendungen

3-Methoxy-2-methylbenzoic acid is used as a Corey-Bakshi-Shibata oxazaborolidine catalyst for asymmetric reduction and asymmetric synthesis. It is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols and propargyl alcohols. It is also used in desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

Literaturverweise

Thi-Huu Nguyen.; Nguyet Trang Thanh Chau.; Anne-Sophie Castanet.; Kim Phi Phung Nguyen.; Jacques Mortier. Toward a Better Understanding on the Mechanism of Ortholithiation. Tuning of Selectivities in the Metalation of meta-Anisic Acid by an Appropriate Choice of Base. J. Org. Chem. 2005, 7 (12), 2445-2448.

Yoshiaki Nakagawaa, , , Kazunari Hattoria, Chieka Minakuchia, Soichi Kugimiyaa, Tamio Ueno. Relationships between structure and molting hormonal activity of tebufenozide, methoxyfenozide, and their analogs in cultured integument system of Chilo suppressalis Walker. Steroids. 2000, 65 (3), 117-123.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
510395
Harmonized Tariff Code
2918.99
TSCA
No

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