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2483-57-0 - Methyl nitroacetate, 98% - Nitroacetic acid methyl ester - L18950 - Alfa Aesar

L18950 Methyl nitroacetate, 98%

CAS-Nummer
2483-57-0
Synonyme
Nitroacetic acid methyl ester

Größe Preis ($) Menge Verfügbarkeit
2g 57,99
10g 194,40
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Methyl nitroacetate, 98%

MDL
MFCD00075480
EINECS
219-622-0

Chemische Eigenschaften

Formel
C3H5NO4
Molmasse
119.08
Siedepunkt
195-198°
Flammpunkt
105°(221°F)
Dichte
1.294
Brechungsindex
1.4260
Sensitivität
Light Sensitive
Löslichkeit
Miscible with ethanol, ether and most organic solvents.

Anwendungen

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Bemerkungen

Light sensitive. Incompatible withstrong bases.

Literaturverweise

Hoffmann, R. C.; Schneider, J. J. Synergistic and Antagonistic Ligand Effects in the Transformation of Silver Compounds of Keto- and Cyano-Functionalised Oximates and Nitronates: A Systematic Study Using Thermal Analysis. Eur. J. Inorg. Chem. 2015, 2015 (25), 4254-4259.

Afreh, I.; Wujcik, E. K.; Blasdel, N.; Sauer, B.; Kaya, S.; Duirk, S.; Monty, C. N. Detection of halogenated organics by their inhibitory action in a catalytic reaction between dimethyl acetylenedicarboxylate and 2-methyl-4-nitroaniline. J. Anal. Chem. 2015, 70 (7), 825-830.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335-H303

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed.

Sicherheitshinweise: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1758670
Harmonized Tariff Code
2915.90
TSCA
No
RTECS
AJ1093000

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