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2627-86-3 - (S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5% - L-(-)-alpha-Methylbenzylamine - L19118 - Alfa Aesar

L19118 (S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%

CAS-Nummer
2627-86-3
Synonyme
L-(-)-alpha-Methylbenzylamine

Größe Preis ($) Menge Verfügbarkeit
5g 23,90
25g 50,70
100g 132,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%

MDL
MFCD00064406
EINECS
220-098-0

Chemische Eigenschaften

Formel
C8H11N
Molmasse
121.18
Schmelzpunkt
-10°
Siedepunkt
187°
Flammpunkt
71°(159°F)
Dichte
0.948
Brechungsindex
1.5260
Sensitivität
Air Sensitive
Löslichkeit
Slightly miscible with water.

Anwendungen

(S)-(-)-1-Phenylethylamine is utilized in a one-pot, multi-component synthesis of a highly substituted, chiral pyrrole.

Bemerkungen

Keep away from sources of ignition. Incompatible with acids, acid chlorides, acid anhydrides and strong oxidizing agents.

Literaturverweise

For use as a chiral auxiliary in the asymmetric synthesis of (R)-(-)-10-methyl-1(9)-octal-2-one, see: Org. Synth. Coll., 9, 610 (1998):

Cassimjee, K. E.; Humble, M. S.; Land, H.; Abedi, V.; Berglund, P. Chromobacterium violaceum ω-transaminase variant Trp60Cys shows increased specificity for (S)-1-phenylethylamine and 4'-substituted acetophenones, and follows Swain-Lupton parameterisation. Org. Biomol. Chem. 2012, 10 (28), 5466-5470.

Cui, S.; Wang, T.; Hu, X. Synthesis, characterization, and DFT studies of a new chiral ionic liquid from (S)-1-phenylethylamine. Spectrochim. Acta, Part A 2014, 133, 778-784.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H311-H302-H314-H318-H227

Toxic in contact with skin. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,6026
Beilstein
2204907
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2921.49
TSCA
Yes

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