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(S)-(-)-1-Phenylethylamine is utilized in a one-pot, multi-component synthesis of a highly substituted, chiral pyrrole.
For use as a chiral auxiliary in the asymmetric synthesis of (R)-(-)-10-methyl-1(9)-octal-2-one, see: Org. Synth. Coll., 9, 610 (1998):
Cassimjee, K. E.; Humble, M. S.; Land, H.; Abedi, V.; Berglund, P. Chromobacterium violaceum ω-transaminase variant Trp60Cys shows increased specificity for (S)-1-phenylethylamine and 4'-substituted acetophenones, and follows Swain-Lupton parameterisation. Org. Biomol. Chem. 2012, 10 (28), 5466-5470.
Cui, S.; Wang, T.; Hu, X. Synthesis, characterization, and DFT studies of a new chiral ionic liquid from (S)-1-phenylethylamine. Spectrochim. Acta, Part A 2014, 133, 778-784.
Gefahrenhinweise (EU): H227-H302-H311-H314-H318
Combustible liquid. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.