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2449-05-0 - Dibenzyl azodicarboxylate, 96% - Azodicarboxylic acid dibenzyl ester - DBAD - L19347 - Alfa Aesar

L19347 Dibenzyl azodicarboxylate, 96%

CAS-Nummer
2449-05-0
Synonyme
Azodicarboxylic acid dibenzyl ester
DBAD

Größe Preis ($) Menge Verfügbarkeit
5g 56,10
25g 201,00
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Dibenzyl azodicarboxylate, 96%

MDL
MFCD00016737
EINECS
219-508-0

Chemische Eigenschaften

Formel
C16H14N2O4
Molmasse
298.30
Schmelzpunkt
43-47°
Flammpunkt
>110°(230°F)
Sensitivität
Light Sensitive

Literaturverweise

Aza-dienophile; the cycloaddition products can be debenzylated by hydrogenolysis: J. Am. Chem. Soc., 109, 285 (1987); 110, 5229 (1988); 111, 2995 (1989). Compare Di-tert-butyl­ azodicarboxyl­ate, L00294, Diethyl­ azodicarboxyl­ate, L19348, and Diisopropyl­ azodicarboxyl­ate, L10386. Effects enantioselective ɑ-amination of aldehydes, mediated by L-Proline, A10199: J. Am. Chem. Soc., 124, 5656 (2002):

/n

For the formation of functionalized ß-amino alcohols by the three-component asymmetric assembly with an aldehyde and a ketone, see: Org. Lett, 5, 1685 (2003).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2298734
Harmonized Tariff Code
2927.00
TSCA
Yes

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