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4-Bromoindole is a potential inhibitor of GSK-3. It is also used as pharmaceutical intermediates.
Yuusaku Yokoyama; Hidemasa Hikawa; Masaharu Mitsuhashi; Aki Uyama; Yasuoki Murakami. Syntheses without protection: a three-step synthesis of optically active clavicipitic acid by utilizing biomimetic synthesis of 4-bromotryptophan. Tetrahedron Letters.1999, 40, 7803-7806.
Mark C Bagley; Christopher J Moody; Adrian G Pepper. Studies towards the synthesis of diazonamide A. Synthesis of the 4-(oxazol-5-ylmethyl) aryltryptamine fragment. Tetrahedron Letters.2000, 41, 6901-6904.