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2799-21-5 - (R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99% - (R)-(+)-3-Pyrrolidinol - L19499 - Alfa Aesar

L19499 (R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99%

CAS-Nummer
2799-21-5
Synonyme
(R)-(+)-3-Pyrrolidinol

Größe Preis ($) Menge Verfügbarkeit
1g 57,10
5g 181,00
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(R)-(+)-3-Hydroxypyrrolidine, 99%, ee 99%

MDL
MFCD00145220

Chemische Eigenschaften

Formel
C4H9NO
Molmasse
87.12
Schmelzpunkt
15°
Siedepunkt
108-110°/8mm
Flammpunkt
>110°(230°F)
Dichte
1.048
Brechungsindex
1.4900
Sensitivität
Air Sensitive & Hygroscopic
Löslichkeit
Soluble in water and methanol.

Anwendungen

(R)-(+)-3-Hydroxypyrrolidine is used in the enantioselective addition of diethylzinc to aromatic aldehydes leading to optically active secondary alcohols. Also used to prepare-κ-opioid receptor agonists.

Bemerkungen

Store under inert gas. It is sensitive to moisture. Store in a cool, dry conditions in well sealed containers. It is hygroscopic and sensitive to air. Incompatible with oxidizing agents.

Literaturverweise

A Naylor.; D B Judd.; D I Scopes.; A G Hayes.; P J Birch. 4-[(Alkylamino)methyl]furo[3,2-c]pyridines: a new series of selective kappa-receptor agonists. Journal of Medicinal Chemistry. 1994, 37 (14), 2138-2144.

Mitsunori Hashimoto.; Yutaka Eda.; Yasutomo Osanai.; Toshiaki Iwai.; Seiichi Aoki. A Novel Decarboxylation of α-amino acids. A Facile Method of Decarboxylation by the use of 2-Cyclohexen-1-one as a Catalyst. Chemistry Letters. 1986, 15 (6), 893-896.

Product of Toray Industries, Inc.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313

Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists:

Weitere Referenzen

Beilstein
5376132
Harmonized Tariff Code
2933.99
TSCA
No

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