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34160-40-2 - 6-Bromopyridine-2-carboxaldehyde, 97% - L19518 - Alfa Aesar

L19518 6-Bromopyridine-2-carboxaldehyde, 97%

CAS-Nummer
34160-40-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 32,04
5g 97,20
25g 416,70
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6-Bromopyridine-2-carboxaldehyde, 97%

MDL
MFCD02683546
EINECS
000-000-0

Chemische Eigenschaften

Formel
C6H4BrNO
Molmasse
186.01
Schmelzpunkt
79-83°
Sensitivität
Air Sensitive
Löslichkeit
Soluble in dichloromethane, ether, ethyl acetate and methanol. Insoluble in water.

Anwendungen

6-Bromopyridine-2-carboxaldehyde is used in the study of a rhodium-catalyzed, reductive aldol coupling with divinyl ketones leading to syn ß-hydroxyenones. It is also used as a building block for Tris[(pyridyl)methyl]amine ligands.

Bemerkungen

Store under inert gas. It is sensitive to air. Store in a cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literaturverweise

Soo Bong Han.; Michael J Krische. Reductive aldol coupling of divinyl ketones via rhodium-catalyzed hydrogenation: syn-diastereoselective construction of beta-hydroxyenones. Organic Letters. 2006, 8 (24), 5657-5660.

Chao-Yu Wang, Yi-Hong Liu, Shei-Ming Peng, Shiuh-Tzung Liu. Rhodium(I) complexes containing a bulky pyridinyl N-heterocyclic carbene ligand: Preparation and reactivity. J. Org. ChemJournal of Organometallic Chemistry. 2006, 691 (19), 4012-4020.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1524300
Harmonized Tariff Code
2933.39
TSCA
No

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