Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

1277-49-2 - (±)-1-Ferrocenylethanol, 99% - 1-Hydroxyethylferrocene - alpha-Methylferrocenemethanol - L19681 - Alfa Aesar

L19681 (±)-1-Ferrocenylethanol, 99%

CAS-Nummer
1277-49-2
Synonyme
1-Hydroxyethylferrocene
alpha-Methylferrocenemethanol

(±)-1-Ferrocenylethanol, 99%

MDL
MFCD00013752

Chemische Eigenschaften

Formel
C12H14FeO
Molmasse
230.09
Schmelzpunkt
77-79°
Flammpunkt
>100°(212°F)
Löslichkeit
Insoluble in water.

Anwendungen

(+/-)-1-Ferrocenylethanol is a ligand in titanium-catalyzed intermolecular hydroamination of terminal alkynes (Markovnikov vs. anti-Markovnikov addition). Used as a reactant for single-electron transfer living radical polymerization reactions, preparation of ferrocene-modified thiopyrimidines as anticancer agents, preparation of rersible addition-fragmentation chain transfer (RAFT) agent for RAFT polymerization of styrene.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

Literaturverweise

Neil W. Boaz. Enzymatic esterification of 1-ferrocenylethanol: An alternate approach to chiral ferrocenyl bis-phosphines. Tetrahedron Letters. 1989, 30, (16), 2061-2064.

Stanley I. Goldberg; William D. Loeble; Thomas T. Tidwell. Alumina-catalyzed dehydration of 1-ferrocenylethanol. Formation of 1,3-diferrocenyl-1-butene. J. Org. Chem. 1967, 32, (12), 4070-4071.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.90
TSCA
No
RTECS
LK0730000

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf