Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

55650-58-3 - (S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97% - L19686 - Alfa Aesar

L19686 (S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

CAS-Nummer
55650-58-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100mg 25,68
500mg 88,34
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

MDL
MFCD00075285

Chemische Eigenschaften

Formel
C26H28FeNP
Molmasse
441.34
Schmelzpunkt
141-143°
Sensitivität
Air Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine is the raw material of asymmetric hydrogenation chiral ligands.

Bemerkungen

Air sensitive. Store under inert gas. Store away from oxidizing agents, air.

Literaturverweise

Keiji Yamamoto; Junya Wakatsuki; Ryuichi Sugimoto. Modification of (S)-N,N-Dimethyl-1-[(R)-1?,2-bis(diphenylphosphino)ferrocenyl]ethylamine (BPPFA) as a Ligand for Asymmetric Hydrogenation of Olefins Catalyzed by a Chiral Rhodium(I) Complex. Bulletin of the Chemical Society of Japan. 1980, 53, (4), 1132-1137.

Masaharu Nakamura; Atsushi Hirai and Eiichi Nakamura. Iron-Catalyzed Olefin Carbometalation. J. Org. Chem. Soc. 2000, 125, (5), 978-979.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.39
TSCA
No

Empfohlen

  • L19685

    (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%
  • 46784

    Silver bis(trifluoromethylsulfonyl)imide

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf