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55650-58-3 - (S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97% - L19686 - Alfa Aesar

L19686 (S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

CAS-Nummer
55650-58-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100mg 25,68
500mg 88,34
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(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%

MDL
MFCD00075285

Chemische Eigenschaften

Formel
C26H28FeNP
Molmasse
441.34
Schmelzpunkt
141-143°
Sensitivität
Air Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

(S)-(+)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine is the raw material of asymmetric hydrogenation chiral ligands.

Bemerkungen

Air sensitive. Store under inert gas. Store away from oxidizing agents, air.

Literaturverweise

Keiji Yamamoto; Junya Wakatsuki; Ryuichi Sugimoto. Modification of (S)-N,N-Dimethyl-1-[(R)-1?,2-bis(diphenylphosphino)ferrocenyl]ethylamine (BPPFA) as a Ligand for Asymmetric Hydrogenation of Olefins Catalyzed by a Chiral Rhodium(I) Complex. Bulletin of the Chemical Society of Japan. 1980, 53, (4), 1132-1137.

Masaharu Nakamura; Atsushi Hirai and Eiichi Nakamura. Iron-Catalyzed Olefin Carbometalation. J. Org. Chem. Soc. 2000, 125, (5), 978-979.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.90
TSCA
No

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