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84680-95-5 - 1,1'-Bis(di-tert-butylphosphino)ferrocene, 98% - L19759 - Alfa Aesar

L19759 1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%

CAS-Nummer
84680-95-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
500mg 67,50
2g 225,00
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1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%

MDL
MFCD01630818

Chemische Eigenschaften

Formel
C26H44FeP2
Molmasse
474.43
Schmelzpunkt
73-78°
Löslichkeit
Insoluble in water.

Anwendungen

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Hanh Nho Nguyen,; Xiaohua Huang,; Stephen L. Buchwald. The First General Palladium Catalyst for the Suzuki-Miyaura and Carbonyl Enolate Coupling of Aryl Arenesulfonates. J. Am. Chem. Soc.. 2003, 125 (39), 11818-11819.

Fawn N. Blanco,; Laura E. Hagopian,; William R. McNamara,; James A. Golen,; Arnold L. Rheingold,; Chip Nataro. Anodic Electrochemistry of Free and Coordinated 1,1‘-Bis(di-tert-butylphosphino)ferrocene. Organometallics. 2006, 25 (18), 4292-4300.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.39
TSCA
No

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