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L19948 N-Boc-1,6-diaminohexane, 98%

CAS-Nummer
51857-17-1
Synonyme
N-(tert-Butoxycarbonyl)hexamethylenediamine
tert-Butyl N-(6-aminohexyl)carbamate

Stock No. Größe Preis ($) Menge Verfügbarkeit
L19948-03 1g 44,50
L19948-06 5g 137,00
L19948-14 25g 537,00
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N-Boc-1,6-diaminohexane, 98%

MDL
MFCD00671489
EINECS
000-000-0

Chemische Eigenschaften

Formel
(CH3)3COCONH(CH2)6NH2
Molmasse
216.33
Siedepunkt
106-110°/0.3mm
Flammpunkt
>110°(230°F)
Dichte
0.965
Brechungsindex
1.4620
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Löslichkeit
Soluble in dichloromethane and ethyl acetate.

Anwendungen

N-Boc-1,6-diaminohexane is used to prepare 1,3-Bis[6-(Boc-amino)hexyl]urea by reacting with carbonyl dichloride in the presence of triethylamine. Further, it is used as a reagent for the introduction of a C6-spacer.

Bemerkungen

Air sensitive. Incompatible with strong oxidizing agents.

Literaturverweise

Jong, T.; Bradley, M. Flow-Mediated Synthesis of Boc, Fmoc, and Ddiv Monoprotected Diamines. Org. Lett. 2015, 17 (3), 422-425.

Jong, T.; Pérez-López, A. M.; Johansson, E. M. V.; Lilienkampf, A.; Bradley, M. Flow and Microwave-Assisted Synthesis of N-(Triethylene glycol)glycine Oligomers and Their Remarkable Cellular Transporter Activities. Bioconjugate Chem. 2015, 26 (8), 1759-1765.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2089264
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2924.19
TSCA
No

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