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80041-89-0 - Isopropylboronic acid, 98% - 2-Propaneboronic acid - L19962 - Alfa Aesar

L19962 Isopropylboronic acid, 98%

CAS-Nummer
80041-89-0
Synonyme
2-Propaneboronic acid

Größe Preis ($) Menge Verfügbarkeit
1g 25,70
5g 80,20
25g 283,00
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Isopropylboronic acid, 98%

MDL
MFCD01319021

Chemische Eigenschaften

Formel
C3H9BO2
Molmasse
87.91
Sensitivität
Hygroscopic
Löslichkeit
Soluble in water.

Anwendungen

Isopropylboronic acid as a reagent is involved in copper-promoted cross-coupling, Domino Heck-Suzuki reactions, Suzuki-Miyaura type couple reactions and alkylation-hydride reduction sequence.

Bemerkungen

Hygroscopic. Incompatible with oxidizing agents.

Literaturverweise

Thorsten Wilhelm; Mark Lautens. Palladium-catalyzed alkylation-hydride reduction sequence: synthesis of meta-substituted arenes. Organic Letters. 2005, 7,(18), 4053-4056.

 

Adri van den Hoogenband; Jos H.M.Lange; Jan Willem Terpstra; Melle Koch; Gerben M.Visser; Martin Visser; Ties J.Korstanje; Johann T.B.H.Jastrzebski. Ruphos-mediated Suzuki cross-coupling of secondary alkyl trifluoroborates. Tetrahedron Letters. 2008, 49,(26), 4122-4124.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1731883
Harmonized Tariff Code
2931.90
TSCA
No

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